Sunday, March 9, 2008

Applications of Gold

As the metal

Medium of monetary exchange

In various countries, gold is used as a standard for monetary exchange, in coinage and in jewelry. Pure gold is too soft for ordinary use and is typically hardened by alloying with copper or other base metals. The gold content of gold alloys is measured in carats (k), pure gold being designated as 24k.

Gold coins intended for circulation from 1526 into the 1930s were typically a standard 22k alloy called crown gold, for hardness. Modern collector/investment bullion coins (which do not require good mechanical wear properties) are typically 24k, although the American Gold Eagle and British gold sovereign continue to be made at 22k, on historical tradition. The Canadian Gold Maple Leaf coin contains the highest purity gold of any popular bullion coin, at 99.999% (.99999 fine). Several other 99.99% pure gold coins are currently available, including Australia's Gold Kangaroos (first appearing in 1986 as the Australian Gold Nugget, with the kangaroo theme appearing in 1989), the several coins of the Australian Lunar Calendar series, and the Austrian Philharmonic. In 2006, the U.S. Mint began production of the American Buffalo gold bullion coin also at 99.99% purity.

Today, gold has fallen out of use in coins made for general circulation.


Jewelry

Because of the softness of pure (24k) gold, it is usually alloyed with base metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. Alloys with lower "k", typically 22k, 18k, 14k or 10k, contain higher percentages of copper, silver or other base metals in the alloy. Copper is the most commonly used base metal, yielding a redder metal. Eighteen carat gold containing 25% copper is found in antique and Russian jewelry and has a distinct, though not dominant, copper cast, creating rose gold. Fourteen carat gold-copper alloy is nearly identical in color to certain bronze alloys, and both may be used to produce police and other badges. Blue gold can be made by alloying with iron and purple gold can be made by alloying with aluminum, although rarely done except in specialized jewelry. Blue gold is more brittle and therefore more difficult to work with when making jewelry. Fourteen and eighteen carat gold alloys with silver alone appear greenish-yellow and are referred to as green gold. White gold alloys can be made with palladium or nickel. White 18 carat gold containing 17.3% nickel, 5.5% zinc and 2.2% copper is silver in appearance. Nickel is toxic, however, and its release from nickel white gold is controlled by legislation in Europe. Alternative white gold alloys are available based on palladium, silver and other white metals (World Gold Council), but the palladium alloys are more expensive than those using nickel. High-carat white gold alloys are far more resistant to corrosion than are either pure silver or sterling silver. The Japanese craft of Mokume-gane exploits the colour contrasts between laminated colored gold alloys to produce decorative wood-grain effects.


Rose gold

Rose gold is a gold and copper alloy widely used for specialized jewelry due to its reddish colour. It is also known as pink gold and red gold. Because it was popular in Russia at the beginning of the nineteenth century it is also known as Russian gold, although this term has become somewhat rare. Since it is an alloy, there is no such thing as "pure rose gold"; pure gold is yellow and pure copper is reddish. Although the names are often used interchangeably, the difference between red, rose, and pink gold is the copper content: The higher the copper content, the stronger the red coloration. A common alloy for rose gold is three-quarters gold and one-quarter copper (18K).

Rose gold is also the name of a commonly-used finish in bell interiors of musical instruments. It consists of a very thin plating of copper over a layer of silver. No actual gold is used. The highest karat version of rose gold is also known as crown gold, which is 22 karat. 18 karat rose gold may be made of 25% copper and 75% gold. For 18 karat rose gold, typically about 4% silver is added to the 75% gold and 21% copper to give a rose color. 14 karat red gold is often found in the Middle East and contains 41.67% copper.


Characteristics

Gold is the most malleable and ductile metal; a single gram can be beaten into a sheet of one square meter, or an ounce into 300 square feet. Gold leaf can be beaten thin enough to become translucent. The transmitted light appears greenish blue, because gold strongly reflects yellow and red.

Gold readily forms alloys with many other metals. These alloys can be produced to increase the hardness or to create exotic colors (see below). Gold is a good conductor of heat and electricity, and is not affected by air and most reagents. Heat, moisture, oxygen, and most corrosive agents have very little chemical effect on gold, making it well-suited for use in coins and jewelry; conversely, halogens will chemically alter gold, and aqua regia dissolves it via formation of the chloraurate ion.

Common oxidation states of gold include +1 (gold(I) or aurous compounds) and +3 (gold(III) or auric compounds). Gold ions in solution are readily reduced and precipitated out as gold metal by adding any other metal as the reducing agent. The added metal is oxidized and dissolves allowing the gold to be displaced from solution and be recovered as a solid precipitate.

Recent research undertaken by Sir Frank Reith of the Australian National University shows that microbes play an important role in forming gold deposits, transporting and precipitating gold to form grains and nuggets that collect in alluvial deposits.[1]

High quality pure metallic gold is tasteless, in keeping with its resistance to corrosion (it is metal ions which confer taste to metals).

In addition, gold is very dense, a cubic meter weighing 19300 kg. By comparison, the density of lead is 11340 kg/m³, and the densest element, iridium, is 22650 kg/m³.

Colour of gold

The usual gray colour of metals depends on their "electron sea" that is capable of absorbing and re-emitting photons over a wide range of frequences. Gold behaves differently, depending on subtle relativistic effects that affect the orbitals around gold atoms.

Malleability

Malleability is a mechanical property of matter, but is most commonly used in reference to metals and metalloids. A malleable metal is capable of being extended, shaped, or otherwise deformed without cracking by the processes of hammering or rolling. This property is important in metalworking, as materials that crack or break under pressure cannot be hammered or rolled. Malleable materials can be formed using stamping or pressing, whereas brittle metals and plastics must be molded.

Malleability occurs as a result of the specific type of bond found in metals (Main article: metallic bond). In metallic bonds, valence shell electrons are delocalized and shared between many atoms. This is often referred to as the "sea of electrons" and is responsible for many properties of metal. The delocalized electrons allow metal atoms to slide past one another without being subjected to strong repulsive forces that would cause other materials to shatter.

Gold is the most malleable metal, followed by aluminium. Many plastics, and amorphous solids such as Play-Doh are also malleable.

It also means changeable, as in "we are all malleable".

Ductility

Ductility is a mechanical property which describes how much plastic deformation a material can sustain before fracture occurs. Examples of highly ductile metals are silver, gold, copper, and aluminium. The ductility of steel varies depending on the alloying constituents. Increasing levels of carbon decreases ductility, i.e. the steel becomes more brittle.

Ductility can be quantified by the fracture strain, which is the strain at which a test specimen breaks during a uniaxial tensile test. Another commonly used measure is the reduction of area at fracture.

The brittle-ductile transition zone is the strongest part of the Earth's crust. For quartz and feldspar rich rocks in continental crust this occurs at an approximate depth of 10-15 km (equivalent to temperatures in the range 350-450°C). At this depth rock becomes less likely to fracture, and more likely to deform ductilely by creep. This happens because the brittle strength of a material is increased by the confining pressure, whilst the ductile strength of a material decreases with increasing temperature. The transition zone occurs at the level in the crust where the downwards increasing brittle strength equals the upwards inreasing ductile strength, giving a characteristic "saw-tooth" crustal strength profile. This zone is, therefore, the strongest part of the crust and the depth at which many earthquakes occur. The level of the transition zone depends on both strain rate and temperature gradient, being shallower for slow deformation and/or high heat flow and deeper for fast deformation and/or low heat flow. Crustal composition will also affect the depth at which this zone occurs.

It is a common misunderstanding that the BDTZ is caused by rock becoming "soft" in the higher temperature of the deep. This is false. Deep rock does not become soft; on the contrary, it becomes harder, more like steel (or prestressed concrete) and less likely to crack under pressure.



Gold

Gold (pronounced /ˈɡoʊld/) is a chemical element with the symbol Au (from the Latin aurum, meaning shining dawn) and atomic number 79. It is a highly sought-after precious metal which, for many centuries, has been used as money, a store of value and in jewelry. The metal occurs as nuggets or grains in rocks, underground "veins" and in alluvial deposits. It is one of the coinage metals. Gold is dense, soft, shiny and the most malleable and ductile of the known metals. Pure gold has a bright yellow color traditionally considered attractive.

Gold formed the basis for the gold standard used before the fiat currency monetary system was employed by the International Monetary Fund (IMF) and the Bank for International Settlements (BIS). It is specifically against IMF regulations to base any currency against gold for all IMF member states. The ISO currency code of gold bullion is XAU.

Modern industrial uses include dentistry and electronics, where gold has traditionally found use because of its good resistance to oxidative corrosion.

Chemically, gold is a trivalent and univalent transition metal. Gold does not react with most chemicals, but is attacked by chlorine, fluorine, aqua regia and cyanide. Gold dissolves in mercury, forming amalgam alloys, but does not react with it. Gold is insoluble in nitric acid, which will dissolve silver and base metals, and this is the basis of the gold refining technique known as "inquartation and parting". Nitric acid has long been used to confirm the presence of gold in items, and this is the origin of the colloquial term "acid test," referring to a gold standard test for genuine value.


79 platinum ← gold → mercury
Ag
↑
Au
↓
Rg
General
Name, Symbol, Number gold, Au, 79
Chemical series transition metals
Group, Period, Block 11, 6, d
Appearance metallic yellow
Standard atomic weight 196.966569(4)  g·mol−1
Electron configuration [Xe] 4f14 5d10 6s1
Electrons per shell 2, 8, 18, 32, 18, 1
Physical properties
Phase solid
Density (near r.t.) 19.3  g·cm−3
Liquid density at m.p. 17.31  g·cm−3
Melting point 1337.33 K
(1064.18 °C, 1947.52 °F)
Boiling point 3129 K
(2856 °C, 5173 °F)
Heat of fusion 12.55  kJ·mol−1
Heat of vaporization 324  kJ·mol−1
Heat capacity (25 °C) 25.418  J·mol−1·K−1
Vapor pressure
P(Pa) 1 10 100 1 k 10 k 100 k
at T(K) 1646 1814 2021 2281 2620 3078
Atomic properties
Crystal structure cubic face centered
Oxidation states −1, 1, 2, 3, 4, 5
(amphoteric oxide)
Electronegativity 2.54 (Pauling scale)
Ionization energies 1st: 890.1 kJ/mol
2nd: 1980 kJ/mol
Atomic radius 135  pm
Atomic radius (calc.) 174  pm
Covalent radius 144  pm
Van der Waals radius 166 pm
Miscellaneous
Magnetic ordering diamagnetic
Electrical resistivity (20 °C) 22.14 n Ω·m
Thermal conductivity (300 K) 318  W·m−1·K−1
Thermal expansion (25 °C) 14.2  µm·m−1·K−1
Speed of sound (thin rod) (r.t.) (hard-drawn)
2030  m·s−1
Young's modulus 78  GPa
Tensile Strain 0.00157  
Shear modulus 27  GPa
Bulk modulus 220  GPa
Poisson ratio 0.44
Mohs hardness 2.5
Vickers hardness 216  MPa
Brinell hardness ? 2450  MPa
CAS registry number 7440-57-5
Selected isotopes
Main article: Isotopes of gold
iso NA half-life DM DE (MeV) DP
195Au syn 186.10 d ε 0.227 195Pt
196Au syn 6.183 d ε 1.506 196Pt
β- 0.686 196Hg
197Au 100% 197Au is stable with 118 neutrons
198Au syn 2.69517 d β- 1.372 198Hg
199Au syn 3.169 d β- 0.453 199Hg
References